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Liquid Epoxy Electronic Packaging Materials

------Two series of liquid Epoxy electronic packaging materials available: 1) Electrically/Thermally Conductive Adhesives, and 2) Liquid Epoxy Underfill and Encapsulants. The main applications include the die attach (Figure 1), Flex interconnects (Figure 2), chip-bonding (Figure 3), underfilling and encapsulating FC-BGA/CSP devices.

Liquid Epoxy Materials for Microelectronic Packaging Applications

Electrically/Thermally Conductive Adhesives

------ZKEP series electrically conductive adhesives (ECA), prepared by mixing of high purity, low viscous, high adhesive epoxy resins with silver plates, and curing agent, catalyst and surfactants, are single component without evolving of organic volatile in thermal curing process, which could be directly used with addition of any other components prior to use.

------ZKEP series thermally conductive adhesives (TCA),prepared by mixing of high purity, low viscous, high adhesive epoxy resins with high thermal conductive powders such as Si3N4, Al2N3, and curing agent, catalyst and surfactants, are single component without evolving of organic volatile in thermal curing process, which could be directly used with addition of any other components prior to use.

------Three issues, i.e the physical properties, application methods and cure conditions of the adhesives should be taken into account before choosing the optimal electrically conductive adhesives or thermally adhesives, because the adhesive features have a big impact on your product performance. It is recommended that the customer should perform a through evaluation for any application based on their specific requirements.

Advantageous Features:

1. Single Components, ,easy processing and handling
2. High purity, low impurity
3. High electrically or thermally conductivity
4. Good adhesion to substrates such as Si, GaAS, SiO2, Si2N3, Cu, Al, Ni
5. Good storage stability

Typical Applications

1. Die attach in hybrid microelectronics, semiconductor packaging and assembly
2. Quartz crystal attach
3. LED attach and interconnetc
4. Flip chip underfill for FC-BGA, FC/CSP,
5. Solder replacement
6. High temp Solder replacement
7. Chip bonding such as chip on leadframe, chip on board, flip chip,
8. Flexible interconnetion in fiber optics, optoelectronics, medical devices, solder replacement

 

Table 1 ZKEP Series Electrically/Thermally Conductive Adhesives
Products ZKEP4010 ZKEP4020 ZKEP4030 ZKEP4040
Components Single
Appearance Silver Liquid Silver Liquid Silver Liquid Gray Liquid
AbsoluteViscosity(mPa·s) 3000 2700 3600 5200
Filler (wt %) 65-72 (Silver) 65-72 (Silver) 65-72 (Silver) 65-72 (AI2O3)
Thixotropic Index 3-5 3-5 3-5 3-5
Storage Stability >6months
(-20 ℃)
>6months
(-20 ℃)
>6months
(-20 ℃)
>6months
(-20 ℃)
Curing Condition 150 ℃/1hr 150 ℃/1hr 150 ℃/1hr 150 ℃/1hr
Pot life 48 hrs 48 hrs 48 hrs 48 hrs
Impurity(pp) Na+ <0.1 <0.1 <0.1 <0.1
K- <5 <5 <5 <5
Cl- <0.2 <0.2 <0.2 <0.2
Tg (℃) 90℃ 110℃ 115℃ 86℃
Moisture Uptakes(%) 0.68 0.56 0.84 0.50
Modulus(GPa) 1.4 1.6 1.4 1.8
CTE(ppm/℃) 45.2 33.9 36.5 54.1
Thermal Conduc.(W/m·℃) 3.2 3.3 3.2 3.3
Elec. Conductivity(×10-4Ω·cm) 1-3 5-7 1-3 1-3
Shear Strength(MPa) ≥5.0 ≥5.0 ≥5.0 ≥5.0

Liquid Epoxy Electronic Packaging Materials

------ZKEP series liquid epoxy electronic packaging materials (LEEP), including FC-BGA/CSP underfill and over encapsulants, prepared by mixing of high purity, low viscous, high adhesive epoxy resins with spherical silica filler, and curing agent, catalyst and surfactants, are single component without evolving of organic volatile in thermal curing process, which could be directly used with addition of any other components prior to use.

------FC-BGA/CSP underfill are highly flowable, high purity, one component liquid, suitable for the gap size and solder bump pitch > 25 µm. After thermally cured, a uniform and void free underfill layer under flipchi devices was formed for protecting the active surface of the die while improving the device reliability by distributing stress away from the solder interconnects.

------Several issues should be taken into account before selecting the optimal underfill and encapsulants, because the adhesive features have a big impact on your product performance. The physical properties, such as viscosity, thixotropic index, and working life, and the curing condition will usually influence on the processing of applying the liquid. Glass transition temperature, shear strength and modulus of the cured materials will affect the product performance. It is recommended that the customer should perform a through evaluation for any application based on their specific requirements.

Advantageous Features:

1. Single Components, easy processing and handling
2. High purity, low impurity
3. low stress, low CTE
4. Good adhesion to substrates such as Si, GaAS, SiO2, Si2N3, Cu, Al, Ni
5. Good storage stability

Typical Applications

1. Flip chip underfill for FC-BGA, FC/CSP
2. Device Encapsulantion
3. Die attach in hybrid microelectronics, semiconductor packaging and assembly
4. Quartz crystal attach
5. LED attach and interconnetc

Table 2 ZKEP Series Liquid Epoxy Underfills
Products ZKEP4110 ZKEP4120 ZKEP4130 ZKEP4140
Components Single
Appearance Viscous Liquid Viscous Liquid Viscous Liquid Viscous Liquid
Absolute Visicosity(Pa·s) 12-14 14-16 6-8 12-14
Filler(wt.%) 65-72 (Silver) 65-72 (Silver) 65-72 (Silver) 65-72 (AI2O3)
Part Gap/PitchSize Filled >25μm >25μm >25μm >25μm
Storage Stability >6 months
(-40℃)
>6 months
(-40℃)
>6 months
(-40℃)
>6 months
(-40℃)
Impurity(ppm) Na+ <3 <3 <3 <3
K- <5 <5 <5 <5
Cl- <6 <6 <6 <8
Tg ( ℃) 100 ℃ 120℃ 145℃ 110℃
Moisture Uptakes(%) < 0.7 <0.6 <0.8 <0.8
Modulus(GPa) 1.5 1.6 1.4 1.8
CTE(ppm/℃) 25 24 27 28
Adhesion Strength(MPa) ≥3.0 ≥3.0 ≥3.0 ≥3.0

Note:

  1. ------ZKEP4110 series are high flowable, high purity, one component underfill. A uniform and void free underfill layer could be formed under flip chip devices, protecting the active surface of the die while improving reliability by distributing stress away from the solder interconnects.
  2. ------ZKEP4120 series are low stress underfill formulated for rapidly flowing under 25 µm gap and for ceremic or laminate substrates where minimal stress is important.
  3. ------ZKEP4130series are low alpha particle emission underfill formulated for rapidly flowing under 25 µm gap and for low stress and low modulus applications.
  4. ------ZKEP4140 are low alpha particle emission underfill formulated for rapidly flowing under 25 µm gap and for high Tg and low CTE applications.
 
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